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Oxygen mix promises to increase fuel cell performance
By R. Colin Johnson
EE TimesApril 11, 2003 (2:09 p.m. EST)
PORTLAND, Ore. — Supercharging fuel cells by premixing the fuel
with oxygen holds out the promise of superslim fuel cells that can
be manufactured on a printing press.
Inventor Generics Group Ltd. (Cambridge, England) believes the new
design, which eliminates the need for bulky metal separation
plates, will shrink the cell size while increasing power density
tenfold.
“The compact mixed-reactant [CMR] fuel cell is a platform approach
that is applicable to every type of fuel cell,” said Michael
Priestnall, technical director of CMR at Generics. “Our premise is
that if you change the catalysts so that they are selective, then
you can relax many of the restraints about not allowing the fuel
and oxygen to mix.”
In normal fuel cells, the fuel and oxygen are kept in separate,
adjacent compartments. In the first compartment, the fuel enters
and reacts with the anode catalyst, which breaks the fuel`s
molecular bonds so that its electrons can flow out the anode to
power equipment. In the second compartment, oxygen flows over the
cathode catalyst, which uses the electricity`s return line from the
load to bond oxygen to the leftover fuel`s free hydrogen, resulting
in water as exhaust.
Platinum is typically the choice for both the anode and cathode,
because it “is very good at doing both fuel oxidation and oxygen
reduction,” said Priestnall. “You need to keep the fuel and the
oxygen completely separate; otherwise they will both react on the
same platinum electrode, producing combustion instead of
electricity.”
To keep the fuel and oxygen separate, traditional fuel cells put
metal flow-field plates between adjacent cells. One side of the
flow-field plate supplies fuel to the anode of the next fuel cell,
while the other side supplies oxygen to the cathode of the previous
fuel cell. The anode and the cathode are separated by a solid
polymer membrane to segregate the fuel and oxygen.
Whereas those traditional designs measure about 2 mm thick,
according to Generics, the CMR fuel cell eliminates the metal
flow-field plate completely and uses a thin, perforated polymer
membrane.
“The membrane material in a typical fuel cell is 100 microns
thick-at a cost of about $300 per square meter. But our perforated
membranes only need to be about 1 micron thick,” Priestnall said.
“The cost of membrane material in a normal fuel cell is over $500
per kilowatt. We have brought that down to $15/kW.”
A selective catalyst allows the mixing of fuel and oxygen. Both the
anode and the cathode of a fuel cell have to be coated with a
catalyst that induces the correct reaction-either breaking down
fuel into hydrogen molecules at the anode or bonding free hydrogen
to oxygen at the cathode with the electrical return line.